Kobunshi Kagaku
Online ISSN : 1884-8079
Print ISSN : 0023-2556
ISSN-L : 0023-2556
Single Crystals and Spherulites of Polyethylene Oxide
I. The Structure of Single Crystals and Spherulites
Nishio HiraiYuhiko YamashitaFumiyoshi Yokoyama
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1964 Volume 21 Issue 236 Pages 724-728

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Abstract
The single crystal of polyethylene oxide is near cubical form and its thickness is about 100 Å, the growth face is (120) plane. It is a tetragonal lamella with the molecular chain perpendicular to the lamellar surface. The radial direction of the spherulite is normal to the (120) plane if it has grown at the temperature higher than about 51°C, and to the (010) plane at the lower temperature. The radial growth rate also changes abruptly at about 51°C.
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© The Society of Polymer Science, Japan
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