Journal of the Mass Spectrometry Society of Japan
Online ISSN : 1880-4225
Print ISSN : 1340-8097
ISSN-L : 1340-8097
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Estimation of Standard Heats of Formation of Organic Even-electron Cations.
Hisao NakataTomoko Kobayashi
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1984 Volume 32 Issue 5 Pages 381-386

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Abstract
A method for the estimation of standard heats of formation ΔHf of some organic, even-electron cations is proposed. The estimation procedure is essentially the same with the one previously reported (Bowen-Williams method), except for substituting a hydrogen atom, instead of a methyl group, of the standard alkyl ion to other functional groups such as OH or NH2. The present method has wider applicability than the Bowen-Williams method, because it can also give ΔHf of higher homologous alkyl ion itself, which, in turn, can be used as a standard value for larger organic ions.
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© 1984 by The Mass Spectrometry Society of Japan
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