1991 Volume 39 Issue 5 Pages 235-238
In order to demonstrate the validity of the protonation susceptibility of pertinent functional groups, the chemical ionization mass spectra were measured for bifunctional aromatic compounds of the type p-XCH2-C6H4-CH2Y, where X=OH and NH2, Y=OCH3 and N(CH3)2. The relative protonation susceptibilities obtained from the observed spectral data are in good agreement with those available from other pairs of compounds reported previously. The order of the susceptibilities is not even qualitatively parallel to that of the proton affinities of these functional groups, and the result therefore indicates the protonation susceptibility being a significant and useful parameter in interpreting the chemical ionization mass spectra.