Mass Spectrometric Investigation of Petroleum(II) Mass Spectrometric Analysis of Monoaromatic Hydrocarbon in Gas Oil.

SHOZO OSHIMA; AKIRA KATSUMATA; KINYA FUJII

doi:10.5702/massspec1953.11.46

Mass Spectrometric Investigation of Petroleum(II)

Mass Spectrometric Analysis of Monoaromatic Hydrocarbon in Gas Oil.

SHOZO OSHIMA, AKIRA KATSUMATA, KINYA FUJII

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1963 Volume 11 Issue 22 Pages 46-50

DOI https://doi.org/10.5702/massspec1953.11.46

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Published: September 25, 1963 Received: May 31, 1963 Available on J-STAGE: June 28, 2010 Accepted: - Advance online publication: - Revised: -
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Date of correction: June 28, 2010 Reason for correction: - Correction: ABSTRACT Details: Wrong : The monoaromatic hydrocarbon fraction separated from Kuwait gas oil cut(210∼330°C)by elusion chromatography was analyzed by thelow voltage ionization method. The sulfur compounds in the fraction were removed by mercuric treatment. The abundance order of hydrocarbon types in the fraction was as follows: monocyclo-alkylbenzene>alkylbenzene>dicyclo-alkylbenzene>tricyclo-alkylbenzene. The total of cycloalkylbenzenes of the fraction was 67.6%, the constitution of this monoaromatic fraction resembled to that of California crude oil. The abundance of cycloalkylbenzenes in paraffinic Kuwait and California crude oil is high and that of cycloalkylbenzenes in non-paraffinic Pennsylvania crude oil is low. It may be expected that the constitution of monoaromatic fraction is related to the types of crude oil. Carbon numbers of alkyl branch of monoaromatic hydrocarbons were five or less than five.
Right : The monoaromatic hydrocarbon fraction separated from Kuwait gas oil cut (210-330 °C) by elusion chromatography was analyzed by thelow voltage ionization method. The sulfur compounds in the fraction were removed by mercuric treatment.
The abundance order of hydrocarbon types in the fraction was as follows: monocycloalkylbenzene > alkylbenzene > dicyclo-alkylbenzene > tricyclo-alkylbenzene.
The total of cycloalkylbenzenes of the fraction was 67.6%, the constitution of this monoaromatic fraction resembled to that of California crude oil. The abundance of cycloalkylbenzenes in paraffinic Kuwait and California crude oil is high and that of cycloalkylbenzenes in non-paraffinic Pennsylvania crude oil is low. It may be expected that the constitution of monoaromatic fraction is related to the types of crude oil. Carbon numbers of alkyl branch of monoaromatic hydrocarbons were five or less than five.

Date of correction: June 28, 2010 Reason for correction: - Correction: CITATION Details: Wrong : E
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Right : M. J. O'Neal, T. P. Wier, Anal. Chem., 23, 830(1951).
H. E. Lumpkin, B. H. Johnson, Anal. Chem., 26, 1719(1954).
M.J.O'Neal,“Applied Mass Spectrometry”pp. 27, (1954), Institute of Petroleum, London.
M.L. André, A Hood, R.T. Longman, M.J. O'Neal,“Mass Spectrometric Analysis of High-Boiling Aromatic Hydrocarbon ”A.S.T.M. Committee E-14 Meeting, San Francisco, Calif., May, 1955.
R. J. Clerc, A. Hood, M. J. O'Neal, Anal. Chem., 27, 868(1955).
S. H. Hastings, B. H Johnson, H. E. Lumpkin, Anal. Chem., 28, 1243(1956).
F. W. Melpolder, R. A. Brown, A. Washall, C. E. Headington, Anal. Chem., 28, 1936(1956).
H. E. Lumpkin, Anal. Chem., 28, 1946(1956).
R. A. Brown, D. J. Skahan, V. A. Cirillo, F. W. Melpolder, Anal. Chem., 31, 1351(1959).
C. J. Varsel, F. A. Morrell, K. E. Resnik, W. Allanpowell, Anal. Chem., 32, 182(1960).
R. J. Clerc, M. J. O'Neal, Anal. Chem., 33, 380(1961).
H. E. Lumpkin, Anal. Chem., 30, 321(1958).
M.L. André, M.J.O'Neal, Anal. Chem., 31, 164(1959).
G. L. Kearns, N. C. Maianowski, G. F. Crable, Anal. Chem., 31, 1646(1959).
G. F. Crable, G. L. Kearns, M. S. Norris, Anal. Chem., 32, 13(1960).
G. H. VonFuchs, Ind. Eng. Chem., 34, 755(1942).
D. Haresnape, Ind. Eng. Chem., 41, 2695(1949).
R. Emmott, J. Inst. Petr., 39, 695(1953).
E. M. Charlet, K. P. Lanneau, F. B. Johnson, Clevland Meeting, Am. Chem. Soc., Petr. Div., 105, April, 1951.

Abstract

The monoaromatic hydrocarbon fraction separated from Kuwait gas oil cut (210-330 °C) by elusion chromatography was analyzed by thelow voltage ionization method. The sulfur compounds in the fraction were removed by mercuric treatment.
The abundance order of hydrocarbon types in the fraction was as follows: monocycloalkylbenzene > alkylbenzene > dicyclo-alkylbenzene > tricyclo-alkylbenzene.
The total of cycloalkylbenzenes of the fraction was 67.6%, the constitution of this monoaromatic fraction resembled to that of California crude oil. The abundance of cycloalkylbenzenes in paraffinic Kuwait and California crude oil is high and that of cycloalkylbenzenes in non-paraffinic Pennsylvania crude oil is low. It may be expected that the constitution of monoaromatic fraction is related to the types of crude oil. Carbon numbers of alkyl branch of monoaromatic hydrocarbons were five or less than five.

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