Atomic Negative Ions Studied by Mass Spectroscopy

TSUTOMU MAKITA; HIROSHI KISHI; KUMASABURO KODERA

doi:10.5702/massspec1953.21.293

TSUTOMU MAKITA, HIROSHI KISHI, KUMASABURO KODERA

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1973 Volume 21 Issue 4 Pages 293-301

DOI https://doi.org/10.5702/massspec1953.21.293

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Published: December 28, 1973 Received: December 27, 1973 Available on J-STAGE: June 28, 2010 Accepted: - Advance online publication: - Revised: -
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unpublished.

Abstract

Atomic negative ions were studied for eighty one different elements by means of double focusing mass spectrograph. Over one hundred twenty different sample materials were ionized by pulsed radio-frequency vacuum spark discharge.Special features for the negative ion mass spectra were discussed and compared with positive ion mass spectra. Fourty eight the elements were detected as atomic negative ions, and the results were discussed with literature values of the electron affinity for the atoms. Chemical analysis by negative ion mass spectra was briefly discussed.

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