Journal of the Mass Spectrometry Society of Japan
Online ISSN : 1880-4225
Print ISSN : 1340-8097
ISSN-L : 1340-8097
The Study of Pyrolytic Products of Polymer Materials by Mass Spectrometry IX. Gaseous Products in the Pyrolysis of Polyurethane Foam
KINJI HIRAMATSU
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1973 Volume 21 Issue 4 Pages 327-332

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Abstract
Under the various conditions of pyrolysis, HCN, CO and other poisonous gases generated from polyurethane foam were examined. The results showed that, under the fuel rich air atmosphere, about 0.1 wt.% and about 4 wt.% of the initial polyurethane foam samples are converted into HCN and CO, respectively. This amount (wt.%) of HCN generated from polyurethane foam is only about 1/60 compared with that generated from polyacrylonitrile.
By the mass spectrometric analysis of the pyrolytic products from polyurethane foam, these products contained lower grade aliphatic hydrocarbons, alcohols, aromatic hydrocarbons and other various compounds and the complete analysis of all components was very difficult.
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