Hydration of Calcined Dolomite in Fructose Solution and Hydrogen Chloride Gas Removal with Its Hydrate
2006 Volume 13 Issue 321 Pages 98-104
Details
2006 Volume 13 Issue 321 Pages 98-104
This study was made to investigate the characterization and HC1 gas removal of calcined dolomite hydrate (mixture of Mg (OH) 2 and Ca (OH) 2) synthesized by hydrating the calcined dolomite with water contained fructose. The calcined dolomite hydrate with ultrafine particles was synthesized by adding fructose solution to the calcined dolomite which was heated the dolomite at 1000°C for 1 hour. The sample was characterized by means of X-ray diffraction, measurements of specific surface area and particle size distribution.
The limestone, which was contained in the dolomite, was dissolved using 0.10 mol dm-3 HC1 solution. The calcined dolomite was obtained by heating the treated dolomite at 1000°C for 1 hour. The calcined dolomite hydrate with ultrafine particle was synthesized by hydrating the calcined dolomite using fructose solution for 6 h, and was a mixture of Ca (OH) 2 and Mg (OH) 2. The specific surface area of the calcined dolomite hydrate increased with the increase of fructose/calcined dolomite mass ratio. In fructose/calcined dolomite mass ratio of 0.07, the specific surface area of the calcined dolomite hydrate was 147 m2·g-1 Ca (OH) 2 and Mg (OH) 2 were uniformly dispersed in sample. The HC1 gas removal ability of the calcined dolomite hydrate was enhanced with increase of specific surface area.
