Journal of the Society of Inorganic Materials, Japan
Online ISSN : 2185-4378
ISSN-L : 1345-3769
Crystal Structure of [NH3 (CH2) 2NH3] HPO4 Synthesized under Hydrothermal Condition
Dan WANGRanbo YUTakahiro TAKEINobuhiro KUMADANobukazu KINOMURA
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2001 Volume 8 Issue 290 Pages 33-36

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Abstract

A new ethylenediammonium monohydrogen-tetraoxophosphate, [NH3 (CH2) 2NH3] 2+ HPO42- has been hydrotherally synthesized and structurally characterized. The crystal structure of the compound consists of layers built up from [HPO4] 2- tetrahedra alternating with layers of the [NH3 (CH2) 2NH3] 2+ dications. In the inorganic layers, [HPO4] 2-groups link together by hydrogen bonds of O-H-O. The inorganic layers and [NH3 (CH2) 2 NH3] 2+ dications link adjacently, forming a network of hydrogen bonds, N-H-O.

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