Journal of Network Polymer,Japan
Online ISSN : 2186-537X
Print ISSN : 1342-0577
ISSN-L : 1342-0577
Original
Synthesis of a Novel Epoxy Resin Based on Indole Oligomer Obtained by Polycondensation Reaction of Indole and Formaldehyde and Properties of its Cured Polymer with Phenol Novolac
Hisashi YamadaKazuhiko NakaharaMasashi Kaji
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2014 Volume 35 Issue 6 Pages 272-278

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Abstract
Indole based epoxy resin(INRE) was synthesized by the reaction of epichlorohydrin and indole oligomer which was obtained by polycondensation reaction of indole and paraformaldehyde. In order to evaluate the effect of indole structure on the thermal properties, o-cresol novolac type epoxy resin was used as reference. The cured polymer of INRE with phenol novolac showed glass transition temperature of 177.8℃ in DMA measurement which was comparable with 184.1℃ of the OCNE polymer, while showed lower storage modulus in the rubbery states. Moisture absorption was 0.15wt% lower than that of the OCNE polymer. This result might be attributed to the aromatic structure and lowering high polar ether moiety in the cured polymer compared with that derived from glycidyl ether.
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© 2014 Japan Thermosetting Plastics Industry Association
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