Japan Thermosetting Plastic Industry Association
Online ISSN : 2186-5361
Print ISSN : 0388-4384
ISSN-L : 0388-4384
Toughening of Epoxy Resin by Modifying with Imide Oligomer
Toughening Mechanism and Curing Condition Dependence of Mechanical Properties
Hajime KISHIAtushi OZAKINobuyuki ODAGIRIAkiko YAMAMOTOKenji YOSHIMURA
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1992 Volume 13 Issue 3 Pages 135-146

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Abstract
The toughened epoxy resin system modified with synthesized amino-terminated imide oligomer has the micro phase separated morphology which shows the oligomer-rich phase, forming continuous phase via the spinodal decomposition.
Detailed observations with a scanning electron microscopy have found the following two energy absorbing mechanisms, accounting for the high toughness.
1) Ductile tearing of the oligomer-rich continuous phase
2) Plastic deformation of the epoxy-rich dispersed phase
The dependence of curing conditins on resin properties have also been researched.
It has been found that gelation at a lower temperature resulted in a shorter periodic distance (or smaller domain sizes), and the resin had higher fracture toughness.
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© Japan Thermosetting Plastics Industry Association
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