Japan Thermosetting Plastic Industry Association
Online ISSN : 2186-5361
Print ISSN : 0388-4384
ISSN-L : 0388-4384
On Base-catalyzed Reaction of Urea with Aromatic Aldehydes
Shigeya TAKEUCHI
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1982 Volume 3 Issue 1 Pages 1-8

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Abstract
The reaction of urea with aromatic aldehydes (X - CHO, X =H, Br, Cl, NO2, OCH3) was carried out in alcohol using potassium hydroxide as a catalyst. In the reaction of urea with aliphatic aldehydes alkylol ureas have been obtained, but in this work the reaction products were alkylethers of p-substitutedbenzylol ureas. and only in the reaction of urea with p-nitrobenzaldehyde at room temperature p-nitrobenzylol urea was obtained. The reaction path was also investigated by thin layer chromatography. From these results, it is assumed that owing to K+and the electron attracting nature of p-substitutedphenyl nuclei the etherification between p-substitutedbenzylol urea and alcohol used as the reaction solvent arises more easily in the reaction of urea with aromatic aldehyde than with aliphatic aldehyde.
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