Journal of Network Polymer,Japan
Online ISSN : 2186-537X
Print ISSN : 1342-0577
ISSN-L : 1342-0577
Microstructures of Acrylate-modified Epoxy Resin Cured with Acid Anhydride
Hiroshi OKUMURA, Masayuki OKOSHI, Kiichi HASEGAWA, Joji KADOTA
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2003 Volume 24 Issue 3 Pages 148-155

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Abstract
The interpenetrating polymer networks (IPNs) formed diglycidyl ether of bisphenol-A (DGEBA) and poly (ethylene glycol) diacrylate (PEGDA) were prepared by simultaneous polymerization techniques. Methylhexahydrophtalic anhydride was used as curing agent for DGEBA. AIBN, BPO or DTBPO was used as radical initiators for PEGDA. The resultant products were analyzed by DMA measurements and AFM observation. As the results, the product induced by AIBN initiators system have phase-separated IPN structure. In the case of BPO initiation systems, sequential IPN was obtained. From, AFM observations, the phase image clearly shows the phase-separated structure between PEGDA and DGEBA domains.
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© Japan Thermosetting Plastics Industry Association
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