Journal of Network Polymer,Japan
Online ISSN : 2186-537X
Print ISSN : 1342-0577
ISSN-L : 1342-0577
Photocrosslinking Polymers Bearing Oxetane Groups-Thermolysis and Dissolution in Water
Haruyuki OKAMURAYoshimi TAJIMAMasamitsu SHIRAI
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2006 Volume 27 Issue 1 Pages 2-9

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Abstract
Three kinds of polymers or oligomers having both an oxetane moiety and a sulfonate ester linkage in a monomer unit were synthesized. The polymers or oligomers were photocrosslinkable when irradiated in the presence of a photoacid generator. The resulting crosslinked polymers and oligomers became soluble in water after thermolysis. Their dissolubility into water was strongly affected by the molecular weight of the polymers or oligomers and the structure of photoacid generators used.
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