The Reaction of Dehydrochlorinated Polyvinyl Chloride with Thiophenol
1972 Volume 1972 Issue 1 Pages 218-220
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1972 Volume 1972 Issue 1 Pages 218-220
The reaction of dehydrochlorinated poly (vinyl chloride) (DHCl-PVC) with thiophenol in tetrahydrofuran(THF) was studied at 30∼170°C under nitrogen. Thiophenol was found to react mainly with allylchlorine of DHCl-PVC at temperatures lower than 120°C and with both double bond of DHCl-PVC and allylchlorine at 170°C. The effects of azobisisobutyronitrile and UV-irradiation were also investigated.
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