The Synthesis of I₃Sn-Mn(CO)₅ and its Laser Raman Spectrum

Abstract

I₃Sn-Mn(CO)₅ has been synthesized bythe reacti, n, fCl3Sn-Mn(CO)5 withNalinTHF, The IR and lase rRaman spectra of I₃Sn-Mn(CO)₅ have been measured, A linear relationship between the Sn-Mn stretching wave number and the electronegativity of X was observed for a series of X8Sa-Mn(CQ)6 compounds(X=Cl, Br, andI), An efect of X on the Sn-Mn bonding nature was discussed based on the CO and MnC stretching frequencies.