NIPPON KAGAKU KAISHI
Online ISSN : 2185-0925
Print ISSN : 0369-4577
Synthesis of Sulfur Dioxide-Acrylic Anhydride Copolymer
Yoshikazu SATOHYoshihiko MUSHATomoyuki TAKESUETadashi IKEMURAMasamichi KATAYAMA
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1982 Volume 1982 Issue 3 Pages 497-499

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Abstract

The copolymerization of sulfur dioxide with acrylic anhydride was carried out in N, N-dimethylformamide or dimethyl sulfoxide using AIBN as an initiator. Copolymer obtained was studied by IR-spectra and elemental analyses. The structure containing a closed ring unit, the SO2 unit in the main chain and a small amount of CH2. CH- group in the side chain was proposed. The thermogravimetry (TG) and the differential scanning calorimetry (DSC) were carried out on the copolymer sample in air. The melting point was not observed and DSC thermogram showed an endotherm at 170∼200°C.

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