Abstract
LiNbO3 is one of dielectric ceramics, and possesses ferroelectricity and a non-linear optic effect. The dielectric characteristic of the compound changes when TiO2 is added. The so-called M-phase solid solutions in the Li2O-Nb2O-TiO2 system were studied by XRD and HRTEM, and the dielectric constants of the compounds were also measured using an impedance analyzer. Characteristic satellite reflections of superstructure were confirmed from the peak of (012) on the XRD profiles.