Fabrication of hybrid materials based on interlayer exchange reactions in layered single-metal hydroxide

Asayo Kasai; Shinobu Fujihara

doi:10.14853/pcersj.2005F.0.622.0

Preprints of Annual Meeting of The Ceramic Society of Japan
Preprints of Fall Meeting of The Ceramic Society of Japan

18th Fall Meeting of The Ceramic Society of Japan & 1st Asia-Oceania Ceramic Federation (AOCF) Conference

Session ID : 2PA29

DOI https://doi.org/10.14853/pcersj.2005F.0.622.0

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Host: The Ceramic Society of Japan

Fabrication of hybrid materials based on interlayer exchange reactions in layered single-metal hydroxide

*Asayo Kasai, Shinobu Fujihara

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Keywords: layered metal hydroxide, intercalation, organic-inorganic hybrid, zinc oxide

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Abstract

Layered basic zinc acetate (LBZA; Zn₅(OH)₈(CH₃COO)₂2H₂O) can be classified into "layered single-metal hydroxide", which is analogous to well-known layered double hydroxides (LDHs). We fabricated LBZA films on substrates through chemical bath deposition and examined their intercalation properties. It was found that neutral ethylene glycol molecules could be inserted between zinc hydroxide layers. We then show potential use of LBZA as organic-inorganic hybrid materials. Thermal decomposition of hybrids to nanostructured zinc oxide is also discussed.

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