Preprints of Annual Meeting of The Ceramic Society of Japan
Preprints of Fall Meeting of The Ceramic Society of Japan
Annual Meeting of The Ceramic Society of Japan, 2006
Session ID : 1D18
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Non-stoichiometrically Activated Sintering for Ca1-xSrxTiO3 by Creating Point Defects with Li2Si2O5
*Ruixing LiQing TangShu YinTsugio Sato
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Abstract
According to both the first principle and materials chemistry, an innovative method for fabricating of the Ca1-xSrxTiO3 ceramics was investigated. Ca1-xSrxTiO3 was sintered at temperatures as low as 980 Degree C by adding 1.0 wt % Li2Si2O5 without forming a grain boundary phase. It was considered that the sintering was promoted by self-accelerated diffusion due to the formation of point defects caused by doping with Li2Si2O5. Consequently, a new concept of non-stoichiometrically activated sintering, which is enhanced by point defects without the help of a grain boundary phase, is systematically studied for the first time in the Ca1-xSrxTiO3- Li2Si2O5 system.
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© The Ceramic Society of Japan 2006
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