Preprints of Annual Meeting of The Ceramic Society of Japan
Preprints of Fall Meeting of The Ceramic Society of Japan
Annual Meeting of The Ceramic Society of Japan, 2007
Session ID : 3C23
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Diffusion Path of Oxide Ions in Apatite-type La9.8(Si5.7Mg0.3)O26.4
*Roushown AliMasatomo YashimaFujio IzumiHideki YoshiokaYoshitaka MatsushitaTakahiro WakitaTakayuki TsujiYoichi KawaikeTakafumi KomatsuYong Phat
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Abstract
Densities of coherent-scattering lengths in apatite-type La9.8(Si5.7Mg0.3)O26.4 (P63/m) have been investigated at 1558 degC by Rietveld refinement and whole-pattern fitting approach based on the maximum-entropy method from neutron powder diffraction data. The Rietveld refinement suggested an interstitial oxygen atom site (0.015,0.207,0.808) accompanied by a slight improved profile fitting results. Nuclear density map derived from the MEM analyses revealed that oxide ions located at 2a site were diffused along the c-axis of the apatite system. In addition, a short range curved diffusion path through the interstitial site was clearly visualized between two oxygen atoms (O3) within the tetrahedra.
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© The Ceramic Society of Japan 2007
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