Preprints of Annual Meeting of The Ceramic Society of Japan
Preprints of Fall Meeting of The Ceramic Society of Japan
21st Fall Meeting of The Ceramic Society of Japan
Session ID : 1G21
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Host: The Ceramic Society of Japan

1H and 7Li NMR study on superionic phase of LiBH4
*Hideki Maekawa, Motoaki Matsuo, Mariko Ando, Yasuto Noda, Hitoshi Takamura, Yuuko Nakamori, Shinichi Orimo
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Keywords: Lithium Ionic Conductor, LiBH4, NMR, Superionic conduction
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Abstract
The electrical conductivity of lithium borohydride (LiBH4) measured by the ac complex impedance method increased by three orders of magnitude due to structural transition from orthorhombic to hexagonal at approximately 390 K. Spin-lattice relaxation time (T1) of 7Li nuclear magnetic resonance (NMR) was in good agreement with the measured electrical conductivity.
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© The Ceramic Society of Japan 2008
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