Preprints of Annual Meeting of The Ceramic Society of Japan
Preprints of Fall Meeting of The Ceramic Society of Japan
22nd Fall Meeting of The Ceramic Society of Japan
Session ID : 1N02
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Self-Organized Nanocrystalline Organosilicates in Organic-Inorganic Hybrid Films
*Masahide TakahashiCristiana FigusPlinio Innocenzi
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Abstract

Organic-inorganic hybrid films containing organosilica nano-crystals have been obtained by an alcohol-free hydrolytic sol-gel process from a mono-functionalized organically modified alkoxide. Kinetically controlled self-organization has been used to design the hybrid nanocomposite films; nanocrystals of around 100 nm in diameter and 4 nm in thickness have been formed in transparent hybrid films. The layered nanocrystals have shown to be oriented within the films which exhibited an optical anisotropy (dn>10-3); the hybrid nanocomposite material has shown to be suitable for micro/nanofabrication by soft lithography and different patterned structured containing the hybrid nanocrystals have been obtained

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© The Ceramic Society of Japan 2009
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