Preprints of Annual Meeting of The Ceramic Society of Japan
Preprints of Fall Meeting of The Ceramic Society of Japan
Annual Meeting of The Ceramic Society of Japan, 2012
Session ID : 3H22
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Preparation of New RE-Sr-Fe (RE=Rare earth) Heteronuclear Complexes and their Thermal Decomposition Product
*Tomoya Kan, Takaaki Nishida, Hiromichi Aono, Yoshihiko Sadaoka, Masato Kurihara, Masatomi Sakamoto
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Keywords: heteronuclear complex, Thermal decomposition, Perovskite, Rare earth, Strontium
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Abstract
We succeeded in synthesis for new (NH4)2XLa1-XSrX[Fe(CN)6]•nH2O (La-Sr-Fe) heteronuclear complex using coprecipitation for (1-X)(NH4)2Sr[FeII(CN)6] and XLa[FeIII(CN)6]•nH2O complexes. The XRD peaks for synthesized complexes moved into higher-angle than peaks of LaFe complexes without peaks of SrFe complexes. The Sr content in synthesized complex was smaller than that of starting material. Furthermore, the La-Sr-Fe complex was synthesized by a mechanochemical process using a planetary ball-mill.
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© The Ceramic Society of Japan 2012
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