Phosphorus Research Bulletin
Online ISSN : 1882-2363
Print ISSN : 0918-4783
ISSN-L : 0918-4783
ASSIGNMENT OF MOBILE PROTON IN PROTON-CONDUCTIVE 15BaO-10PbO-5SrO-70P2O5 GLASS PREPARED BY MICROWAVE HEATING
Kenichi ImaedaYutaka MinamiMakoto SakuraiMakoto Watanabe
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JOURNAL FREE ACCESS

2008 Volume 22 Pages 22-26

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Abstract
15BaO-10PbO-5SrO-70P2O5 phosphate glass has been prepared by 2.45 GHz microwave heating by changing temperature of glass formation and their physical properties have been investigated by 31P MAS NMR, 1H MAS NMR and AC conductivity. The four bands named as band-A, band-B, band-C and band-D were observed in 1H MAS NMR spectra. The band-A and band-B originate in protons in the glass, whereas band-C and band-D originate in protons in adsorbed water on the surface of glass. From the result that AC conductivity increases with increase of the intensity of band-B and decreases with increase of the intensity of band-A, proton for band-B can be assigned to be mobile proton.
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© 2008 Japanese Association of Inorganic Phosphorus Chemistry
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