Phosphorus Research Bulletin
Online ISSN : 1882-2363
Print ISSN : 0918-4783
ISSN-L : 0918-4783
SYNTHESIS OF NOVEL MANGANESE PHOSPHATE VIOLET PIGMENT
Hiroaki ONODA Shiho KANAI
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2020 Volume 36 Pages 23-28

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Abstract
Novel violet pigments were synthesized from manganese oxide and phosphoric acid by heating at several temperatures. The obtained materials were investigated by X-ray diffraction (XRD) analysis, infrared (IR) spectroscopy, X-ray photoelectron spectroscopy (XPS), ultraviolet-visible (UV-Vis) reflectance spectroscopy, and L*a*b* color space. Samples synthesized in this study did not show the XRD peak pattern for certain compounds. At P/Mn = 2/3 and 1/1, samples heated at 500 °C showed high a* value and low b* value, corresponding to violet color. On the other hand, at P/Mn = 2/1, the sample heated at 400 °C had the most violet powder.
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© 2020 Japanese Association of Inorganic Phosphorus Chemistry
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