Phosphorus Research Bulletin
Online ISSN : 1882-2363
Print ISSN : 0918-4783
ISSN-L : 0918-4783
FLUCTUATION MICROINHOMOGENEITIES IN PHOSPHATE GLASSES
Anatoli ANAN'EVViktor BOGDANOVNatal'ya KONONOVALeonid MAKSIMOVSerdei SMERDIN
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2002 Volume 13 Pages 67-72

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Abstract

Na2O-Al2O3-P2O5 and Na2O-K2O-Al2O3-Ga2O3-P2O5 glasses were investigated with Rayleigh and Mandel'shtam-Brillouin scattering (RMBS) spectroscopy and high temperature ultrasonic study (HTUS). RMBS spectra intensities, their ratios and spectral shifts were determined as functions of glass compositions. Using the model of “freezing” of concentration, density, and anisotropy fluctuations in the process of cooling of a glass forming melt it was found that Rayleigh scattering losses are presumably a function of chemical microinhomogeneity of phosphate glasses. Low-scattering glass compositions were found.

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© Japanese Association of Inorganic Phosphorus Chemistry
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