Phosphorus Research Bulletin
Online ISSN : 1882-2363
Print ISSN : 0918-4783
ISSN-L : 0918-4783
HARDENED MATERIAL OF CALCIUM-ALUMINO-SILICATE GLASS AND CALCIUM PHOSPHATE BY HYDROTHERMAL TREATMENT
Seishi GOTOMasao HIRATAToyoyasu OBANAKoji IOKU
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1994 Volume 4 Pages 95-98

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Abstract
Three kinds of glasses in the system CaO-Al2O3-SiO2 with different compositions were mixed with calcium phosphate powders. The mixture was formed into cylindrical shape, and then treated hydrothermally at the temperatures from 100 to 250°C under the saturated vapor pressure of water. The mixture of glasses and β-tricalcium phosphate (β-TCP) could be hardened under hydrothermal conditions. The hardened material prepared at 250°C from the CaO-rich glass and β-TCP had a compressive strength of about 40 MPa. According to XRD and SEM observation for the hardened material, hydroxyapatite fine crystals were precipitated in its matrix.
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© Japanese Association of Inorganic Phosphorus Chemistry
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