1995 Volume 5 Pages 109-114
Silica-alumina was modified by phosphoric acid, and the resulting materials (SiAP) were investigated in terms of catalytic activity and selectivity for n-butene isomerization as well as physicochemical properties. The activity of SiAP catalysts outgassed at 400°C increased sharply with increasing amount of phosphoric acid added, and reached a maximum at 4.8% H3PO4: the maximum activity value was about twice of that of the original silica-alumina. This enhancement in activity was accounted for by an increase in Bröonsted acid sites.