A Note on the Standard Electron Transfer Potential at the Interface between Two Immiscible Electrolyte Solutions

Abstract

This article presents a brief note on the standard electron transfer potential at the interface between two immiscible electrolyte solutions (ITIES) in relation to the standard electrode potentials for redox reactions at electrodes. Based on the available experimental data, the scale of the standard electrode potentials for several redox systems in 1,2-dichloroethane is established, which can be used to evaluate the equilibrium constants of the homogeneous electron transfer reactions.