Nihon Reoroji Gakkaishi
Online ISSN : 2186-4586
Print ISSN : 0387-1533
ISSN-L : 0387-1533
An Empirical Equation on a Shift Factor for Synthesizing Master Curves from Nonlinear Viscoelasticity Functions Based on Free Volume
Takuji YAMAGUCHISusumu SAEKIJunpei YAMANAKA
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1991 Volume 19 Issue 4 Pages 192-196

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Abstract
Ferry and Stratton proposed a relation between a shift factor and a strain. They assumed compressibility of free volume on the basis of a sample volume. On the other hand, we defined the compressibility on the basis of the free volume, and derived a new relation between the shift factor and the strain (or stress). The equation we obtained was different in the formula from the Ferry-Stratton equation, but the properties of the equations were quite similar. Our equation could satisfactorily approximate a relation between the shift factor and the strain for relaxation curves of a polyethylene film, and also the relation between the shift factor and the stress for creep curves of monofilaments of nylon and poly (ethyleneterephthalate). Fractions of free-volume were estimated from these equations.
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© The Society of Rheology, Japan
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