Journal of Society of Cosmetic Chemists of Japan
Online ISSN : 1884-4146
Print ISSN : 0387-5253
ISSN-L : 0387-5253
Effect of Temperature on the H. L. B. Number of Polyoxyethylene Cetyl Alcohol Ether
Teruo HoriuchiToshihiro Jin-noIchiro Kashiwa
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1979 Volume 13 Issue 1 Pages 25-28

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Abstract
The temperature-dependence of the H. L. B. number of plyoxyethylene cetyl alcohol ether (POECAE) was studied from the relative viscosity of its aqueous solution. The measuraments were done by Ubbelode-type viscometer at the temp erature range of 20-70°C, of which results were applied to Jones and Dole's equation. It was found that:
(1). The viscosity B-coefficient of POECAE was dependent on the temperature. It decreased with the increase of temperature. This seems to be due to the breakage of hydration shell.
(2). A good corelationship existed between viscosity-B-coefficient and H. L. B. value.
(3). Since the viscosity B-coefficient decreased with the increase of temperature, the hydrophobic properties increase and the H. L. B. value of POECAE changes to a lower value.
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