Proceeding of Annual/Fall Meetings of the Japan Petroleum Institute
61st R&D Symposium of Jpn. Petrol. Inst.
Session ID : C16
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Oligomerization of ethylene using α-diiminenickel(II) complex immobilized into fluorotetrasilicic mica interlayer
*Hideki Kurokawa, Kazuki Miura, Kazuhiro Yamamoto, Tsutomu Sakuragi, Masa-aki Ohshima, Hiroshi Miura
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Abstract
Oligomerization of ethylene was performed using the α-diiminenickel(II) complex immobilized into fluorotetrasilicic mica interlayer in the presence of triethylaluminum  The activity decrased with an decrease of the steric bulk around the active center.  The steric bulk also affected the product distribution, and the low steric bulk favored the formation of α-olefins.
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© 2012 The Japan Petroleum Institute
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