The Journal of Silk Science and Technology of Japan
Online ISSN : 1881-1698
Print ISSN : 1880-8204
ISSN-L : 1880-8204
Graft polymerization onto silk pretreated with a mercaptosilane
YOUICHI KAMIISHIHIDEKAZU KOMATSUMASANORI OHTATAKEHIRO IWASAKIKATSUAKI ISHIIHIDETAKA TAMAMURA
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1996 Volume 5 Pages 42-47

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Abstract

  Graft polyrmerization using a redox initiation system of potassium peroxidisulfate and 2-hydroxyethylmethacrylate onto silk fibroin fiber pretreated with 3-mercaptopropyl trimethoxysilane was investigated. The pretreatment was performed in the mixed solution of isopropyl alcohol (IPA) and water, and varied the ratio of IPA/water and time of pretreatment. The values of graft-on for the pretreatment system were larger than that of non-pretreatment system. Deposited polymer for grafted silk pretreated in IPA only system was observed on the surface of the fiber by means of scanning electron microscope.

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© 1996 by The Japanese Society of Silk Science and Technology
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