Abstract
The effects of various manufacturing conditions on powdering characteristics were investigated. Powdering is suppressed by an increase in Al content of the bath, a decrease in the bath temperature and a decrease in the galvannealing temperature. All of these conditions tend to delay the alloying progress. In the case of low Al content (0.12%), ζ-phase (FeZn13) abruptly, appears and forms homogeneous layer at the initial stage of alloying, and then completely changes into δ1-phase (FeZn7) in a short period. When the Al content is high (0.16%), the alloying progress is slow and ζ-phase appears heterogeneously at localized spots with time lags. The ζ-phase which appeared late remains unchanged up to the δ1-phase. As the hardness of ζ-phase is lower than that of δ1-phase, the ζ-phase deforms preferentially and relaxes a part of stress induced by forming, therefore powdering is suppressed.