1992 Volume 78 Issue 1 Pages 97-104
The kinetics of nitrogen desorption from liquid Fe-Cr alloys under reduced pressure have been studied at 1600°C.
The nitrogen desorption rate was described by the 2nd order reaction with respect to nitrogen content under these conditions.
The overall nitrogen desorption rate constant, kov decreased with the increase in sulfur and chromium contents.
Assuming the mixed control model, the apparent interfacial reaction rate constant, k[N], is proportional to ƒN1.2ƒN3.2.
The rate of nitrogen desorption seemed to be controlled by the interfacial chemical reaction under the present conditions.