Transactions of the Materials Research Society of Japan
Online ISSN : 2188-1650
Print ISSN : 1382-3469
ISSN-L : 1382-3469
Regular Papers
Adsorption States and Properties of Tellurobenzoate Films on Gold
Tohru Nakamura
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2014 Volume 39 Issue 2 Pages 177-180

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Abstract
  Adsorption states of tellurobezoates having telluro-carbonyl group were studied on Au(111) by X-ray photoelectron spectroscopy (XPS) and atomic force microscopy (AFM) measurements. XPS spectra show that the molecules form organic tellurium-oxide layers. Acids such as trifluoroacetic and sulfuric acid accelerate an accumulation of tellurium-oxide species originating from Te-phenyl tellurobenzoate molecules to cover the surfaces with thick layers, which indicate relatively high resistances. Conductive AFM revealed the high resistance of accumulated tellurium-oxide films and the disruptive strength against dielectric breakdown.
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© 2014 The Materials Research Society of Japan
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