Syntheses and Structures of Keggin-Type Polyoxometalate Crystals Hybridized with a Polymerizable Ionic-Liquid

Saki Otobe; Yoshiki Kiyota; Tatsuhiro Kojima; Yoshiki Oda; Shinichi Koguchi; Yosuke Okamura; Masashi Higuchi; Masaki Kawano; Yu Nagase; Takeru Ito

doi:10.14723/tmrsj.46.15

Regular Papers

Syntheses and Structures of Keggin-Type Polyoxometalate Crystals Hybridized with a Polymerizable Ionic-Liquid

Saki Otobe, Yoshiki Kiyota, Tatsuhiro Kojima, Yoshiki Oda, Shinichi Koguchi, Yosuke Okamura, Masashi Higuchi, Masaki Kawano, Yu Nagase, Takeru Ito

Author information

Saki Otobe
Department of Chemistry, School of Science, Tokai University
Yoshiki Kiyota
Department of Chemistry, School of Science, Tokai University
Tatsuhiro Kojima
Division of Advanced Materials Science, Pohang University of Science and Technology (POSTECH)
Department of Chemistry, Graduate School of Science, Osaka University
Yoshiki Oda
Technology Joint Management Office, Tokai University, Tokai University
Shinichi Koguchi
Department of Chemistry, School of Science, Tokai University
Yosuke Okamura
Department of Applied Chemistry, School of Engineering, Tokai University
Masashi Higuchi
Department of Applied Chemistry, School of Engineering, Tokai University
Masaki Kawano
Division of Advanced Materials Science, Pohang University of Science and Technology (POSTECH)
Department of Chemistry, Graduate School of Science and Engineering, Tokyo Institute of Technology
Yu Nagase
Department of Applied Chemistry, School of Engineering, Tokai University
Takeru Ito
Department of Chemistry, School of Science, Tokai University

Keywords: Inorganic-organic, Hybrid crystal, Polymerizable, Ionic-liquid, Polyoxometalate

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2021 Volume 46 Issue 1 Pages 15-18

DOI https://doi.org/10.14723/tmrsj.46.15

[Correction] J-STAGE : tmrsj 46 1 pp.e1

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Abstract

Keggin-type polyoxometalate clusters were successfully hybridized with a polymerizable ionic-liquid having methacryloyl group and imidazolium moieties (denoted as MAImC₁). Metatungstate ([H₂W₁₂O₄₀]⁶⁻, H₂W₁₂) and dodecamolybdophosphate ([PMo₁₂O₄₀]³⁻, PMo₁₂) anions were firstly employed to obtain inorganic-organic hybrid crystals. Their compositions and structures were clearly revealed by single crystal structure analyses.

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