Crystal Structure of Isothiocyanato-N,N′-diethyl-N,N′-bis(pyridine-2-ylmethyl)propanediaminecopper(II) Perchlorate

Takashi YOKOYAMA; Shintaroh HASE; Masakazu YOSHISE; Atsushi SHIOMI; Takuya SHIBA; Haruo AKASHI; Michio ZENKI

doi:10.2116/xraystruct.27.65

Part 11

Crystal Structure of Isothiocyanato-N,N′-diethyl-N,N′-bis(pyridine-2-ylmethyl)propanediaminecopper(II) Perchlorate

Takashi YOKOYAMA, Shintaroh HASE, Masakazu YOSHISE, Atsushi SHIOMI, Takuya SHIBA, Haruo AKASHI, Michio ZENKI

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Supplementary material

2011 Volume 27 Pages 65-66

DOI https://doi.org/10.2116/xraystruct.27.65

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Abstract

A new complex of an isothiocyanato-N,N′-diethyl-N,N′-bis(pyridine-2-ylmethyl)propanediaminecopper(II) perchlorate ([Cu(NCS)(LEt₂)]ClO₄) was prepared. Its crystal structure was determined by single-crystal X-ray diffractometry. [Cu(NCS)(LEt₂)]ClO₄·0.5H₂O crystallized in a monoclinic system, and was characterized thus: C2/c, with a = 20.8501(10), b = 17.2174(9), c = 15.0630(7)Å, β = 119.049(3)°, Z = 8, V = 4727.2(4)Å³. The crystal structure was solved by direct methods and refined by full-matrix least squares on F² to final values of R1 = 0.0585.

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