Crystal Structure of Bis(μ-hydroxo)diiron(II) Complex with a Dinucleating Ligand Having a Butyl Linker

Mio SEKINO; Hideki FURUTACHI; Kyosuke TASAKI; Takanao ISHIKAWA; Shuhei FUJINAMI; Shigehisa AKINE; Yoko SAKATA; Masatatsu SUZUKI; Takashi NOMURA; Takashi OGURA; Teizo KITAGAWA

doi:10.2116/xraystruct.35.5

Part 2

Crystal Structure of Bis(μ-hydroxo)diiron(II) Complex with a Dinucleating Ligand Having a Butyl Linker

Mio SEKINO, Hideki FURUTACHI, Kyosuke TASAKI, Takanao ISHIKAWA, Shuhei FUJINAMI, Shigehisa AKINE, Yoko SAKATA, Masatatsu SUZUKI, Takashi NOMURA, Takashi OGURA, Teizo KITAGAWA

Author information

Mio SEKINO
Department of Chemistry, Division of Material Sciences, Graduate School of Natural Science and Technology, Kanazawa University
Hideki FURUTACHI
Department of Chemistry, Division of Material Sciences, Graduate School of Natural Science and Technology, Kanazawa University
Kyosuke TASAKI
Department of Chemistry, Division of Material Sciences, Graduate School of Natural Science and Technology, Kanazawa University
Takanao ISHIKAWA
Department of Chemistry, Division of Material Sciences, Graduate School of Natural Science and Technology, Kanazawa University
Shuhei FUJINAMI
Department of Chemistry, Division of Material Sciences, Graduate School of Natural Science and Technology, Kanazawa University
Shigehisa AKINE
Department of Chemistry, Division of Material Sciences, Graduate School of Natural Science and Technology, Kanazawa University
Nano Life Science Institute (WPI-NanoLSI), Kanazawa University
Yoko SAKATA
Department of Chemistry, Division of Material Sciences, Graduate School of Natural Science and Technology, Kanazawa University
Masatatsu SUZUKI
Department of Chemistry, Division of Material Sciences, Graduate School of Natural Science and Technology, Kanazawa University
Takashi NOMURA
Picobiology Institute, Graduate School of Life Science, University of Hyogo
Takashi OGURA
Picobiology Institute, Graduate School of Life Science, University of Hyogo
Teizo KITAGAWA
Picobiology Institute, Graduate School of Life Science, University of Hyogo

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Supplementary material

2019 Volume 35 Pages 5-7

DOI https://doi.org/10.2116/xraystruct.35.5

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Abstract

The structure of the dinuclear Fe(II) complex [Fe₂(OH)₂(L^Bu)]²⁺ (1) was determined by X-ray crystallography, where L^Bu is N,N,N′,N′-tetrakis(6-methyl-2-pyridylmethyl)-1,4-diaminobutane. The compound crystallizes in a monoclinic space group, P2₁/a, with a = 21.678(3), b = 16.3791(16), c = 22.447(3)Å, β = 111.522(2)°, Z = 4, V = 7414.5(14)Å³. The R1 [I > 2σ(I)] and wR2 (all data) values were 0.0474 and 0.1274, respectively, for all 16779 independent reflections. The complex has a bis(μ-hydroxo)diiron core structure.

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