Part 9
Crystal Structure of Hexakis(quinoline-2-thiolatosilver(I))
2019 Volume 35 Pages 51-53
Details
2019 Volume 35 Pages 51-53
The structure of a hexanuclear silver(I) complex with six quinoline-2-thiolato (2-qnt−) ligands [Ag6(C9H6NS)6] (1) has been synthesized and characterized. Complex 1 crystallized in a triclinic space group P-1 (No. 2) with a = 8.064(6), b = 13.480(3), c = 13.573(5)Å, α = 113.528(15)°, β = 104.24(3)°, γ = 100.46(3)°, V = 1244.5(11)Å3, Z = 1, T = 150 K. The R1 [I > 2σ(I)] and wR2(all data) values are 0.032 and 0.089, respectively, for all 4437 independent reflections. The complex has a paddle-wheel-like structure with a trigonally distorted Ag6 octahedral metal core.
