Synthesis and Crystal Structure of (μ-Acetato)bis(μ-Alkoxo)dicobalt(II, III) Complex with an Unsymmetric Dinucleating Ligand

Naho SHINDE; Ryunosuke HANDA; Hideki FURUTACHI; Yoko SAKATA; Shigehisa AKINE; Shuhei FUJINAMI; Masatatsu SUZUKI

doi:10.2116/xraystruct.37.13

Part 3

Synthesis and Crystal Structure of (μ-Acetato)bis(μ-Alkoxo)dicobalt(II, III) Complex with an Unsymmetric Dinucleating Ligand

Naho SHINDE, Ryunosuke HANDA, Hideki FURUTACHI, Yoko SAKATA, Shigehisa AKINE, Shuhei FUJINAMI, Masatatsu SUZUKI

Author information

Naho SHINDE
Department of Chemistry, Division of Material Sciences, Graduate School of Natural Science and Technology, Kanazawa University
Ryunosuke HANDA
Department of Chemistry, Division of Material Sciences, Graduate School of Natural Science and Technology, Kanazawa University
Hideki FURUTACHI
Department of Chemistry, Division of Material Sciences, Graduate School of Natural Science and Technology, Kanazawa University
WPI Nano Life Science Institute (WPI-NanoLSI), Kanazawa University
Yoko SAKATA
Department of Chemistry, Division of Material Sciences, Graduate School of Natural Science and Technology, Kanazawa University
WPI Nano Life Science Institute (WPI-NanoLSI), Kanazawa University
Shigehisa AKINE
Department of Chemistry, Division of Material Sciences, Graduate School of Natural Science and Technology, Kanazawa University
WPI Nano Life Science Institute (WPI-NanoLSI), Kanazawa University
Shuhei FUJINAMI
Department of Chemistry, Division of Material Sciences, Graduate School of Natural Science and Technology, Kanazawa University
Masatatsu SUZUKI
Department of Chemistry, Division of Material Sciences, Graduate School of Natural Science and Technology, Kanazawa University

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Supplementary material

2021 Volume 37 Pages 13-14

DOI https://doi.org/10.2116/xraystruct.37.13

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Abstract

The structure of the dinuclear Co(II, III) mixed-valence complex [Co^IICo^III(tpdb)(CH₃CO₂)(CH₃O)](ClO₄)₂·0.75CH₃OH·0.25CH₃CN (1) was determined by X-ray crystallography, where tpdb is N,N,N′,N′-tetrakis(2-pyridylmethyl)-1,4-diamino-2-butanolate. The compound crystallizes in the monoclinic space group, P2₁/c, with a = 10.4372(4), b = 27.8578(10), c = 13.5496(5)Å, β = 102.8116(10), Z = 4, V = 3841.6(2)Å³. The R1 [I > 2σ(I)] and wR2 (all data) values are 0.0398 and 0.1035, respectively, for all 6799 independent reflections. The complex has a (μ-acetato)bis(μ-alkoxo)dicobalt(II, III) core structure.

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