The theory of ionic diffusion in water-saturated porous solids with surface electric charges has been constructed by using the general theory of diffusion, Gauss’s law, and the condition of electrical neutrality. The theory derives the diffusion rate of ions not from the gradient of the ionic concentration but from the gradient of the chemical potential of ions. The chemical potential is obtained by rigorously solving the Poisson-Boltzmann equation that is derived by connecting the general theory of diffusion and the condition of electrical neutrality with Gauss’s law. Application of the theory to the ionic diffusion from an outer solution into a pore solution surrounded by two parallel charged plates indicates that the maximum concentration of ions penetrable into the pore solution is lower than that of the outer solution, though the penetration rate is not much affected by the surface charge. A simple approximation method of calculating the diffusion rate without solving the Poisson-Boltzmann equation is presented.

The Fukushima Daiichi Nuclear Power Plant lost its core cooling function due to the massive tsunami generated by the 2011 off the Pacific coast of Tohoku Earthquake, which caused core meltdown, resulting in high temperature inside the containment vessel and exposing the RPV pedestal, a reinforced concrete structure, to an unusually high temperature environment. After the earthquake, water was poured into the containment vessel to cool the molten core, and the con-crete structure was gradually cooled in the process. Since it will take at least 40 years to remove the fuel from the core, the integrity of the RPV pedestal is a major concern for the decommissioning of the Fukushima Daiichi Nuclear Power Plant. In order to assess the long-term integrity of the RPV pedestal, a horizontal loading test was conducted using a 1/6 scaled model of the RPV pedestal of Unit 1 considering the effect of the high temperature heating and subsequent wet conditions. And then, the static stress analysis of the RPV pedestal was performed considering the degradation phenomena revealed by the experiments. As a result, it was confirmed that the RPV pedestal of Unit 1 would be structurally sound for 40 years against the current design basis earthquake even if the material degradation due to severe accident and aging was considered.

Countermeasures against carbon dioxide emissions are a concern in the construction field as well as in society. To solve this problem, a concept for new calcium carbonate concrete is proposed, and this concept is validated experimentally. In the proposed concept, calcium carbonate comprising Ca originating from demolished concrete or other Ca-containing industrial wastes and HCO₃^- from CO₂ gas collected from the air or emitted by industrial plants acts as a binder for aggregates, which can be natural rocks or crushed demolished concrete. This short paper describes the details of the process of making calcium carbonate concrete and discusses future perspectives.

As the nuclear fleet in the United States ages and subsequent license renewal applications grow, the prediction of concrete durability at extended operation becomes more important. To address this issue, a Fast-Fourier Transform (FFT) method is utilized to simulate aging-related degradation of concrete within the Microstructure Oriented Scientific Analysis of Irradiated Concrete (MOSAIC) software. MOSAIC utilizes compositional phase maps to simulate damage from radiation-induced volumetric expansion (RIVE), applied force, creep, and thermal expansion. This compositional detail allows each mineral in the microstructure to be assigned specific material properties, allowing the simulation to be as accurate and representative as possible. The principal goal of MOSAIC is to simulate the effects of nonlinear aging mechanisms occurring in nuclear concrete on the macroscopic mechanical properties, using only the aggregate microstructure compositional information as a starting point. Several realistic example simulations are shown to demonstrate the utility and uniqueness of the MOSAIC software.