The efficiency of TiO
2-V
2O
5 catalyst for selective catalytic reduction (SCR) of NO
x was investigated using a single-cylinder direct-injection diesel engine. Ammonium carbonate solution and urea solution were mixed with exhaust gas as deoxidizer instead of NH
3 gas injection. The catalyst provided a substantial reduction in NO
x emissions for a catalyst bed temperature of about 190-430°C. NO
x removal rate was about 70-95% for a space velocity of 6300-12500 h
-1, catalyst temperature of : 350-400°C and NH3 molar ratio of 1-2. Reaction at temperatures above 400°C induced combustion of NH
3 and catalyst sintering. It was recommended that the urea solution be used as deoxidizer in practical application to achieve high denitration efficiency and low leakage of NH
3. However, injection of urea solution caused an increase of Bosch smoke pollution and a reduction of SO
2 concentration due to the emission of sulfate dust produced by reaction of leakage NH
3 with SO
2 and particulate matter (PM). The PM contained a relatively large amount of Na
+, K
+ and SO
4--, which contribute to deterioration of catalyst efficiency, and therefore the PM had a significant effect on the catalyst activity.
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