The dynamic characteristics of shock absorbers, key components of suspensions, significant impact on the vehicle's driving performance, including stability and ride comfort. The damping force of a shock absorber is composed of both hydraulic damping force and friction. Notably, when switching between reciprocating motions, the dynamic friction force becomes the dominant factor. This study found that dynamic performance can be improved by controlling the friction waveform during reciprocating motion through the combination of ZDDP and ester additives with different valences. It was found that the dynamic performance can be improved by controlling the friction waveform during reciprocating motion by combining ZDDP with ester additives of different valences. The aim of this study was to clarify the mechanism by which the friction waveform changes depending on the valence of the ester additive. To achieve this, we investigated the adsorption behavior using a Quartz Crystal Microbalance (QCM), observed the film formation process with Atomic Force Microscopy (AFM), and evaluated friction characteristics using a macro friction tester. This approach allowed us to link nano- and macro-scale characteristics. The results suggest that the reaction of ZDDP on the sliding surface was influenced by changes in the adsorption behavior of the ester additive, which varied depending on its valence. This change in adsorption behavior controlled the friction waveform.
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