Efficient Syntheses of the OPC Homologous Series, OPC-1:0, -3:0, -4:0, -5:0, -6:0, -7:0, and -8:0

Hiroaki TOSHIMA; Shinji NARA; Hisateru ARAMAKI; Akitami ICHIHARA; Yasunori KODA; Yoshio KIKUTA

doi:10.1271/bbb.61.1724

Bioscience, Biotechnology, and Biochemistry

Online ISSN : 1347-6947
Print ISSN : 0916-8451

Efficient Syntheses of the OPC Homologous Series, OPC-1:0, -3:0, -4:0, -5:0, -6:0, -7:0, and -8:0

Hiroaki TOSHIMA, Shinji NARA, Hisateru ARAMAKI, Akitami ICHIHARA, Yasunori KODA, Yoshio KIKUTA

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Keywords: jasmonoid, octadecanoid, 12-oxo-PDA, OPC, 1, 4-conjugate addition

JOURNAL FREE ACCESS

1997 Volume 61 Issue 10 Pages 1724-1728

DOI https://doi.org/10.1271/bbb.61.1724

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Abstract

The OPC homologous series was synthesized from 2-[(Z)-2-pentenyl]cyclopenten-1-one in short steps and with high yields. The carbon-carbon bond formation was achieved by the 1, 4-conjugate addition approach. This method makes it possible to supply a sufficient amount of OPC homologues which would enable significant information to be collected for plant physiological studies.

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