有機合成化学協会誌
Online ISSN : 1883-6526
Print ISSN : 0037-9980
ISSN-L : 0037-9980
ラウンジ
アシルラジカルの極性から想起した新反応開発
柳 日馨
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2016 年 74 巻 8 号 p. 826-831

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With a strong desire to develop radical carbonylation chemistry, we naturally focused our attention on the key reactive intermediate, the acyl radical. Acyl radicals have been regarded as nucleophilic radicals towards electron-poor alkenes, akin to vinyl radicals. However, deeming that acyl radicals may act as pseudo-carbonyl compounds, we observed acyl radicals to behave as electrophilic species, very unlike vinyl radicals. This essay is a personal account of the area of acyl radical chemistry.

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