Journal of The Adhesion Society of Japan
Online ISSN : 2187-4816
Print ISSN : 0916-4812
ISSN-L : 0916-4812
Original Paper
Physical Properties of The Crystalline Cured Polymer Obtained fromBisphenol F Type Epoxy Resin
Masashi KAJIKoichiro OGAMI
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2021 Volume 57 Issue 6 Pages 227-233

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Abstract

It was found that among the bisphenol F type epoxy resins, the highly symmetrical 4,4ʼ-substituted compound(

p-BPF-E) gives a crystalline cured product with a melting point of 149.7℃. As a result of evaluating

the physical properties of the p-BPF-E cured product in the epoxy resin composition filled with alumina, the

thermal conductivity was 4.1 W/m·K( Al2O3; 90 wt%), which was about 1.3 times that of the amorphous cured

product. In addition, the p-BPF-E cured product had high thermal conductivity from room temperature to

around its melting point of 150℃, corresponding to its crystallinity. In addition, it was confirmed that it has a

heat distortion temperature of 154-163℃, low thermal expansion and low water absorption due to the crystallinity

of the cured product.

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© 2021 The Adhesion Society of Japan
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