Analytical Sciences
Online ISSN : 1348-2246
Print ISSN : 0910-6340
ISSN-L : 0910-6340
Rapid Communications
Emission Intensity Modulation of Radio-Frequency Helium Glow-Discharge Emission Source by Laser Ablation
Hideyuki MATSUTATariq M. NAEEMKazuaki WAGATSUMA
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2003 Volume 19 Issue 6 Pages 813-814

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Abstract

A novel emission excitation source comprising a high repetition rate diode-pumped Q-switched Nd:YAG laser and a Grimm-style glow-discharge lamp is described. Laser-ablated atoms are introduced into the He glow discharge plasma, which then give emission signals. By using phase-sensitive detection with a lock-in amplifier, the emission signal modulated by the pulsed laser can be detected selectively. It is possible to estimate only the emission intensity of sample atoms ablated by laser irradiation with little interference from the other species in the plasma.

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© 2003 by The Japan Society for Analytical Chemistry
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