Analytical Sciences
Online ISSN : 1348-2246
Print ISSN : 0910-6340
ISSN-L : 0910-6340
Original Papers
Retrospective Analyses of Atmospheric Polycyclic and Nitropolycyclic Aromatic Hydrocarbons in an Industrial Area of a Western Site of Japan
Naoya KISHIKAWAAyuko IHARAMasae SHIROTAMitsuhiro WADAYoshihito OHBANobuyuki SERAKenichiro NAKASHIMANaotaka KURODA
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2005 Volume 21 Issue 12 Pages 1467-1470

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Abstract

Thirteen polycyclic aromatic hydrocarbons (PAHs) and four nitropolycyclic aromatic hydrocarbons (NPAHs) on the surfaces of airborne particulates, which were collected at an industrial area of a western site of Japan during periods from 1976 to 1998, were retrospectively analyzed. PAHs and NPAHs were extracted from airborne particulates using hexane with ultrasonication, and then analyzed by HPLC systems with fluorescence detection and chemiluminescence detection, respectively. The total concentrations (mean ± SD, n = 34) were 15.54 ± 21.24 ng/m3 for PAHs and 5.85 ± 8.16 pg/m3 for NPAHs. The concentrations of PAHs and NPAHs were found to be highest during the period between 1979 and 1982, and then reduced. The annual concentrations of PAHs and NPAHs were highly correlated with those of air pollutants from motor vehicle origin, such as carbon monoxide, suspended particulates and non-methane hydrocarbons. The results suggested that motor vehicle emissions were one of the predominant sources of atmospheric PAHs and NPAHs.

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© 2005 by The Japan Society for Analytical Chemistry
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