Analytical Sciences
Online ISSN : 1348-2246
Print ISSN : 0910-6340
ISSN-L : 0910-6340
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Synthesis and Characterization of a Chitosan-bearing Binucleating Ligand and Its pH Dependency on Copper(II) Adsorption
K. R. KRISHNAPRIYAM. KANDASWAMY
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JOURNAL FREE ACCESS

2008 Volume 24 Issue 8 Pages 1045-1048

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Abstract
A novel chitosan derivative has been synthesized by the condensation of a binucleating ligand, 2,6-bis[(N-methylpiperazine-1-yl)methyl]-4-formylphenol (BNL), with chitosan (CTS). The resulting material (CTS-BNL) was characterized and its adsorption properties towards copper(II) ions in aqueous solutions of various pH have been studied, the adsorption capacity (Qe) is about 0.94 mmol g-1 at pH 6 and 1.45 mmol g-1 at pH 8.5. This higher adsorption capacity may be due to the binucleating ligand anchored to chitosan.
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© 2008 by The Japan Society for Analytical Chemistry
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